ࡱ> ]\za%oOyy@( ww`!N>͕3d @ "xJA$F 9D" bcgD/@3$`aaa)"XY>J@1C\ػgv:*+v'iKMB0y 1$Mz\7D^eF{0O!uc xQ2]O7RCT."08.znV:uv5|?:GKkSm{7򕅮xlE'Y9j{TG|U[^"}r.amTgmB.dj4)ٓĶ yȻ45Deȇ"ᎣM݁xe ߉VZOSDqwRJ3Ez)!7q?qQM7ps&sRqb_V`!aB ;)kh2@C/xJ@DiE+PSċGEھ@ VL+4 =z)|>GԳh/.Lϗ,X9K*lT!VJO0tb.j-(ӄ~iٖT]&i/tYÜ|q,|,jMy?{2QtI{FqaLy c?[* }/ԗ6S oH6M6Sd%ɞ&_NiyNw$w";Yr<0Z/7N (  L Equation Equation.30,Microsoft Equation 3.0 Equation Equation.30,Microsoft Equation 3.0/ 0DTimes New Roman(0(z[ 0 DMonotype Sorts(0(z[ 0  DSymbole Sorts(0(z[ 0 @ .  @n?" dd@  @@`` `(  +( ?r$%oOyy@i2$N>͕3di2$B ;)khiMs AA1?@8 g4CdCd@z[ 0ppp@ <4BdBdl 0Fʚ;ʚ;<4ddddl|- 0Xr0___PPT10 2___PPT9/ 0? %+Reflection Absorption Infrared Spectroscopy,+$ Experimental Sample Adsorbed on Metal Surface Infrared Beam Aligned at Grazing Incidence Metal Surface Constrains Observed Incident Radiation and Dipole Orientation Advantages Allows Identification of Chemical Species Provides Information on Orientation of Adsorbates L ] ] VIncident Radiation Interacts with Adsorbate Layer and Reflects From the Metal Surface WW  *Dipole Selection Rule for RAIRS on Metals  +* $ [Only Dipole Moments With Contribution Along Surface Normal Interact with Incident Radiation\\   hElectric Field Effects and Driving Force for Vibrational Excitation Determine Optimal Angle of Incidence(i"F   ` f3` f̙` 999___` f3f3f3!>?" dd@,?uKd@  d @uA` d n?" dd@   @@``@n?" dd@  @@``PR    @ ` ` p>> 0 F(     Z0Fgֳgֳ ?P F T Click to edit Master title style! !:  TFgֳgֳ ? F RClick to edit Master text styles Second Level Third Level Fourth Level Fifth Level!     S   `tFgֳgֳ ?0 P F Z*j  BԔ?,T   `xFgֳgֳ ?`` F X*J  Z0Fgֳgֳ ?0 P  F P*University of Illinois Urbana-Champaign))(H  0޽h? ? 999___ hozfinal.pot  og@(    Z0mdgֳgֳ ?  d T Click to edit Master title style! !  Todgֳgֳ ? `   d W#Click to edit Master subtitle style$ $   `|tdgֳgֳ ?@0 O d Z*j  BԔ?,T   `ydgֳgֳ ?`` d X*J  Z!dgֳgֳ ?0 P  d P*University of Illinois Urbana-Champaign))(H  0޽h? ? 999___  P(  q@  l  C F P  F l  C tF `  F H  0޽h ? 999___U     $ ( | $l $ C F P  F | $ c TA0Light downward diagonal f& . $  Sf LB $ c $DSLB $ c $DSZ LB $@ c $DSZ RB  $@ s *D 3SLB  $ c $D Z  z   $ 3   S Vacuum n1 = 1*   $ 3   $Adsorbate n2  ik2@     $ 3 l &  $Substrate n1  ik3@    $ 3 D3 KE1i,  RB $ s *DS $ bBC@DEFx@@ P $ C % @  >E3   $ 3 *  KE2r,   $ 3 .   KE2i,   $ 3 33M KE1r,   $ C $9  >q H $ 0޽h ? 999___  qi`(    s Agֳgֳ ? @   F f   f Z  s *1?  rB  B1? M rB  B1? ) rB   B1?C ) rB   B1?M ) rB   B1?XW 7 rB   B1? G M C rB   B1?I $I C ~B  N1? @ 0 rB B B1?G G C ~B  N1?@ I Y xB  H1?0 0@ rB B B1?g f7 2  C E$GH I`TQ1? `TT`TT`T`T`TT`T`TQ Q A   TGgֳgֳ?   HER||(  TMgֳgֳ? H  GEr^(  T gֳgֳ?k 6 V  HEr||(  T~gֳgֳ?6f  GEi^(  T܂gֳgֳ? 6 V  HEi||(  T`gֳgֳ?V av  GEi^(  Tlfgֳgֳ? HEi||(  T,lgֳgֳ?  3qxB  H1?`0 P rB B B1?7M3 rB  B1? ,    Tp1?   MOnly Parallel Component of Incident Radiation Contributes to Observed Signal NLH  0޽h ? 999___  p)*Z(  l  C $ p(   FB  S Dm  |  c TA0Light downward diagonal ` |  c TA0Light downward diagonal M  .2    .2   = C |   c TA0Light downward diagonal  42   # p 42   #   42   #  9 42   # / 42  # / Y`   S 0   1-42  #    S ԜpV  1+  S 蟂m  Q + -(    S L }  L + -    S بip  G +    S }  5 -  S xf  : + -   S  fS  : - +   S = ##  =+    S ] C  1-FB  S D    bB CDEF  H@ V s   S $ S  4q(t)  S p‚ =  >q   S ǂ @]  1=  S ʂ Tq cos q*   S h΂ M Tq sin q*RB ! s *D--V XB " 0D m XB # 0٠)D    $ S Ԃ$p`-  4q(t)RB % s *D6`` FB &@ S D 9  LB ' c $D   ( S Pق( s=  f S0(w)@  ) S x߂) j 8Monopole  * S  * j 6DipoleH  0޽h ? 999___  %' ( %cwXu    s dWgֳgֳ ? @   pB  H1?P pB  H1?P @P pB  H1?p P 2  S BOENGvwHqIJQ1? }=u-O}=u-OJ`Tu-OJ`T j   2  C BTENG IKQ1? TT`TTT`TK`TT`TK`TP q pB  H1?p 2  s BSENGHis[I#JQ1? íV`TSLYTíV`TSLYT#SLYT# ~ 2  s BSCQENGHKJQ1? `T`TSkQ`T`TSkQSkQr a     BHC3DEF$1?+1GGG2@P[vB  N1? 0 pB  H1?pB  H1?    Tgֳgֳ?&* 250  T(gֳgֳ? &*  225  T<gֳgֳ?I0 12  Tp=dgֳgֳ?   11  Z@dgֳgֳ?`Gg  9 Amplitude   TEdgֳgֳ?A 6: ( 230  THdgֳgֳ?A f j ( 260  TLdgֳgֳ?A DH( 290  THBdgֳgֳ?A 6( 10  ZOdgֳgֳ?/  9 Intensity   T[dgֳgֳ? U  3qpB  @ H1?  pB  H1?` @`    NA ?? X $ 0U 0   NA ?? w X $ 0U 0pB  H1?P vB ! N1? pB " H1?  pB # H1?P0PpB $ H1?P 0P pB % H1? P pB & H1? P  ' Thcdgֳgֳ?6  BAngle of IncidenceH  0޽h ?O@     999___xW]h\E>s&D&kטJ 5GĢHEWdېQIJvoP yCÃ A<(&R샔B-(K} lZk593songT%'99gۋ߶\?E/0aXQj\&O⸹CIc<כq44h;ܓ"eq> 3w||yM79e?L@&aJyk5|_9rD3dxi6p~뎞{ ?|M F A.eFiOs Ƨw䦧r^Qxe8Tp}Sawzyt>P0oW(FQH}ߖܪc+T@凳A~8BإaZ O-R zB|yfHѩ?o!8yR#;'gGJ]:AF$(FZ/Gtcghy,gXV}Yc>, d!@,,+5kf5kEtY5kNvY5u6\l ʉj 7T]fPkUa:{'i G'wi"!>¡-"u"4 h}9%xn 7Ѕ ;_;-Sp.>5;RESkO_joIxXkA3moChZj{"`GH{IiJmT  xP,~K C/zxznZ?K&3{f~!o9 :tL)M\=Ţ.V埒oXjjX{TKtd !Ha=Y'RA.y6п zLNi.^̞T- o'6>Yqt}O󿥈4khT}FG4ci Ɯa°CCvAṕ2CV>"')/݆0nRN\.BQ)&#@n:9 ʏv)iǤgʺxP{ <Сv6=,Ѷ+ G3ukr N83qՊ0n\]|D2į"z2nE sOJ(nZ&5P4JcdLzM.zc\/|m3ChPF&3;DzL< )Mqkp9?É+szZBLBOz옥h>WIqe%ǡzk vsG~3w3,9v >B)g{J BQ[hLƛG҈:=([X#pekVH42F^/]ݼv}g*9I;r-^r0 s)y<i,nSO? q !Oh+'0< hp  0 < HT\,Reflection Absorption Infrared SpectroscopyAuthorized CustomerX:\Temp\Erhardt\hozfinal.potd SLaurent D. Menardzf1urMicrosoft PowerPointnal@P[@wқ@%bUGg  cH  -- @ !--'--086-6-6-,44,,3+3+3+)22))--'-- @ !2g6--'@Times New Roman-. 32 IUniversity of Illinois Urbanai         ."Systemdi-@Times New Roman-.  2 *-.-@Times New Roman-. 2 0 Champaign   .-@Times New Roman-. 62 fReflection Absorption Infrared n!  $   .-@Times New Roman-. 2 n Spectroscopy.-@Monotype Sorts-.  2 Uu!.-@Times New Roman-. 2 { Experimental !  .-@Times New Roman-.  2 .-@Times New Roman-. 72  Sample Adsorbed on Metal Surface     #   .-@Times New Roman-.  2 @.-@Times New Roman-. F2 @*Infrared Beam Aligned at Grazing Incidence            .-@Times New Roman-.  2 x.-@Times New Roman-. H2 x+Metal Surface Constrains Observed Incident #          .-@Times New Roman-. 72  Radiation and Dipole Orientation          .-@Monotype Sorts-.  2 Uu!.-@Times New Roman-. 2 { Advantages  .-@Times New Roman-.  2 .-@Times New Roman-. E2 )Allows Identification of Chemical Speciest         .-@Times New Roman-.  2 W.-@Times New Roman-. B2 W'Provides Information on Orientation of             .-@Times New Roman-. 2  Adsorbates    .-S՜.+,0    On-screen Show -sHA  Times New RomanMonotype SortsSymbol hozfinal.potMicrosoft Equation 3.0,Reflection Absorption Infrared SpectroscopyWIncident Radiation Interacts with Adsorbate Layer and Reflects From the Metal Surface +Dipole Selection Rule for RAIRS on Metals \Only Dipole Moments With Contribution Along Surface Normal Interact with Incident RadiationiElectric Field Effects and Driving Force for Vibrational Excitation Determine Optimal Angle of Incidence  Fonts UsedDesign TemplateEmbedded OLE Servers Slide Titles)_qLaurent D. MenardLaurent D. Menard  !"#$%&'()*+,-./0123456789:;<=>?@ACDEFGHIJKMNOPQRSUVWXYZ[^Root EntrydO)PicturesCurrent UserTSummaryInformation(BlPowerPoint Document(rDocumentSummaryInformation8L